The effects of N-heterocyclic ligands on the nature of the Ru–(NO) bond in ruthenium tetraammine nitrosyl complexes

Summary: Quantum chemical calculations at the DFT level have been carried out to analyze quantitatively the RuII–(NO)+, RuIII–(NO)0 and RuII–(NO)0 bonds in trans-[RuII(NH3)4(L)(NO)]q and trans-[RuII(NH3)4(L)(NO)]q−1 complexes, where L = 4-picoline (4-pic), C-bound imidazole (imC), N-bound imidazole...

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Permalink: http://skupni.nsk.hr/Record/nsk.NSK01000733113/Description
Matična publikacija: Croatica chemica acta
82 (2009), 1 ; str. 219-232
Glavni autor: Caramori, Giovanni F. (-)
Ostali autori: Frenking, Gernot (-)
Vrsta građe: Članak
Jezik: eng
Predmet:
Online pristup: Croatica Chemica Acta