Two compounds with trans-[Mo(NCS)4(y-pic)2]– anion
Summary: By refluxing a mixture of (NH4)2[MoCl5(H2O)] and KSCN in γ-picoline, crystalline trans-[(γ-pic)2H][Mo(NCS)4(γ-pic)2] (1) was prepared. After addition of P(C6H5)4Br to the solution of 1 in acetonitrile, trans-[P(C6H5)4][Mo(NCS)4(γ-pic)2]·2CH3CN (2) was isolated. Both compounds were character...
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| Matična publikacija: |
Croatica chemica acta 82 (2009), 3 ; str. 567-571 |
| Glavni autor: | Kitanovski, Nives (-) |
| Ostali autori: | Golobič, Amalija (-), Čeh, Boris |
| Vrsta građe: | Članak |
| Jezik: | eng |
| Predmet: | |
| Online pristup: |
Croatica Chemica Acta |
| LEADER | 01691caa a2200289 ir4500 | ||
|---|---|---|---|
| 001 | NSK01000734720 | ||
| 003 | HR-ZaNSK | ||
| 005 | 20130307094941.0 | ||
| 007 | ta | ||
| 008 | 100426s2009 ci ||| ||eng | ||
| 035 | |9 (HR-ZaNSK)737342 | ||
| 035 | |a (HR-ZaNSK)000734720 | ||
| 040 | |a HR-ZaNSK |b hrv |c HR-ZaNSK |e ppiak | ||
| 042 | |a croatica | ||
| 080 | |a 54 |2 MRF 1998. | ||
| 100 | 1 | |a Kitanovski, Nives | |
| 245 | 1 | 0 | |a Two compounds with trans-[Mo(NCS)4(y-pic)2]– anion / |c Nives Kitanovski, Amalija Golobič, and Boris Čeh. |
| 300 | |b Ilustr. | ||
| 504 | |a Bibliografija: 26 jed | ||
| 520 | 8 | |a Summary: By refluxing a mixture of (NH4)2[MoCl5(H2O)] and KSCN in γ-picoline, crystalline trans-[(γ-pic)2H][Mo(NCS)4(γ-pic)2] (1) was prepared. After addition of P(C6H5)4Br to the solution of 1 in acetonitrile, trans-[P(C6H5)4][Mo(NCS)4(γ-pic)2]·2CH3CN (2) was isolated. Both compounds were characterized by IR spectroscopy, and their crystal structures were determined. X-ray structural analysis revealed the presence of trans-[Mo(NCS)4(γ-pic)2]– anions, with N-bonding of the NCS groups in both compounds. The positions of the ν(CN) and δ(NCS) bands are in agreement with the crystal-structure results. The results of analyses were compared with the results of the related trans-(py2H)[Mo(NCY)4py2] (Y = S,O) complexes | |
| 653 | 0 | |a Molibden |a γ-pikolin |a Kristalna struktura |a Röntgenska strukturna analiza | |
| 700 | 1 | |a Golobič, Amalija | |
| 700 | 1 | |a Čeh, Boris | |
| 773 | 0 | |t Croatica chemica acta |x 0011-1643 |g 82 (2009), 3 ; str. 567-571 |w nsk.(HR-ZaNSK)000001621 | |
| 981 | |b B02/09 | ||
| 998 | |a Luko100426 |c vol2o130307 | ||
| 856 | 4 | 2 | |u http://hrcak.srce.hr/cca |y Croatica Chemica Acta |