The study of capacitance change during electrolyte penetration through carbon-supported hydrous ruthenium oxide prepared by the sol-gel procedure

Summary: The changes in capacitive behavior of C/HxRuOy composite material prepared by impregnating the Vulcan® XC 72R carbon black with oxide sols of different particle size are investigated as the electrolyte penetrates through the thin layer of the Nafion®-covered composite. The techniques of cyc...

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Matična publikacija: Chemical and biochemical engineering quarterly
23 (2009), 1 ; str. 23-30
Glavni autor: Panić, V. V. (-)
Ostali autori: Dekanski, Aleksandar (-), Mišković-Stanković, Vesna, Nikolić, B. Ž
Vrsta građe: Članak
Jezik: eng
Predmet:
Online pristup: Chemical and Biochemical Engineering Quarterly
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042 |a croatica 
080 |a 66  |2 MRF 1998. 
100 1 |a Panić, V. V. 
245 1 4 |a The study of capacitance change during electrolyte penetration through carbon-supported hydrous ruthenium oxide prepared by the sol-gel procedure /  |c V. V. Panić, A. B. Dekanski, V. B. Mišković-Stanković, B. Ž. Nikolić. 
300 |b Ilustr. 
504 |a Bibliografija: 31 jed 
520 8 |a Summary: The changes in capacitive behavior of C/HxRuOy composite material prepared by impregnating the Vulcan® XC 72R carbon black with oxide sols of different particle size are investigated as the electrolyte penetrates through the thin layer of the Nafion®-covered composite. The techniques of cyclic voltammetry and electrochemical impedance spectroscopy are used. Results of the investigation reveal the influence of potential cycling and the exposure time to the electrolyte on registered capacitive characteristics of composite. The cycling in a wide potential range causes the decrease in energy storage ability which depends on oxide particle size. Impedance measurements, however, show that the ability initially decreases and subsequently increases during exposure to the electrolyte as the consequence of the presence of Nafion® top-layer. Due to wettability and resistance issues, Nafion® top-layer can affect the pseudo-capacitive characteristics, and the energy storage ability of the composite consequently decreases 
653 0 |a Skladištenje energije  |a Elektroliti  |a Nafion  |a Sol-gel postupak 
700 1 |a Dekanski, Aleksandar 
700 1 |a Mišković-Stanković, Vesna 
700 1 |a Nikolić, B. Ž. 
773 0 |t Chemical and biochemical engineering quarterly  |x 0352-9568  |g 23 (2009), 1 ; str. 23-30  |w nsk.(HR-ZaNSK)000004762 
981 |b B03/09 
998 |a Luko100511  |c vol2o121009 
856 4 2 |u http://hrcak.srce.hr/cabeq  |y Chemical and Biochemical Engineering Quarterly