Supramolecular architecture of chloranilate salts with organic cations
Four novel salts of chloranilic acid (H2CA; 3,6-dichloro-2,5-dihydroxy-1,4-quinone) with organic cations pyridinium (Hpy+), piperazinediium (H2ppz2+), 4,4'-bipyridinediium (H2bpy2+) and 1,10-phenanthrolinium (Hphen+) were prepared and structurally characterised: (Hpy)2CA (1), (H2ppz)CA (2), (H2...
| Permalink: | http://skupni.nsk.hr/Record/nsk.NSK01001074256/Details |
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| Matična publikacija: |
Croatica chemica acta (Online) 92 (2019), 2 ; str. 297-305 |
| Glavni autori: | Molčanov, Krešimir (Author), Jurić, Marijana, Androš Dubraja, Lidija |
| Vrsta građe: | e-članak |
| Jezik: | eng |
| Predmet: | |
| Online pristup: |
https://doi.org/10.5562/cca3537 Hrčak |
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| 003 | HR-ZaNSK | ||
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| 007 | cr|||||||||||| | ||
| 008 | 200916s2019 ci a |o |0|| ||eng | ||
| 024 | 7 | |2 doi |a 10.5562/cca3537 | |
| 035 | |a (HR-ZaNSK)001074256 | ||
| 040 | |a HR-ZaNSK |b hrv |c HR-ZaNSK |e ppiak | ||
| 041 | 0 | |a eng |b eng | |
| 042 | |a croatica | ||
| 044 | |a ci |c hr | ||
| 080 | 1 | |a 54 |2 2011 | |
| 100 | 1 | |a Molčanov, Krešimir |4 aut | |
| 245 | 1 | 0 | |a Supramolecular architecture of chloranilate salts with organic cations |h [Elektronička građa] : |b [pi]-stacking vs. hydrogen bonding / |c Krešimir Molčanov, Marijana Jurić, Lidija Androš Dubraja. |
| 300 | |b Ilustr. | ||
| 504 | |a Bibliografija: 41 jed. | ||
| 504 | |a Abstract. | ||
| 520 | |a Four novel salts of chloranilic acid (H2CA; 3,6-dichloro-2,5-dihydroxy-1,4-quinone) with organic cations pyridinium (Hpy+), piperazinediium (H2ppz2+), 4,4'-bipyridinediium (H2bpy2+) and 1,10-phenanthrolinium (Hphen+) were prepared and structurally characterised: (Hpy)2CA (1), (H2ppz)CA (2), (H2bpy)CA·4H2O (3) and (Hphen)HCA·MeOH (4). Supramolecular architecture is based on extensive hydrogen bonding and π-stacking. The central motive is chloranilate dianion which acts as an acceptor of two bifurcated hydrogen bonds. Topology and dimensionality of hydrogen bonded networks can be tuned by use of different cations: thus discrete motives, 1D chains and 2D layers were observed. Three different types of π-stacks are present: aromatic stacks, quinoid stacks and stacks of alternating quinoid and aromatic rings. | ||
| 546 | |b Grčko slovo u naslovu. | ||
| 653 | 0 | |a Kloranilna kiselina |a Kristalne strukture |a Supramolekularna kemija |a Vodikove veze |a Kationi |a Anioni |a Prijenos protona |a Elektronska struktura | |
| 700 | 1 | |a Jurić, Marijana |4 aut | |
| 700 | 1 | |a Androš Dubraja, Lidija |4 aut | |
| 773 | 0 | |t Croatica chemica acta (Online) |x 1334-417X |g 92 (2019), 2 ; str. 297-305 |w nsk.(HR-ZaNSK)000255036 | |
| 981 | |b Be2019 |b B05/19 | ||
| 998 | |b tino2011 | ||
| 856 | 4 | 0 | |u https://doi.org/10.5562/cca3537 |
| 856 | 4 | 0 | |u https://hrcak.srce.hr/228429 |y Hrčak |
| 856 | 4 | 1 | |y Digitalna.nsk.hr |